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DC Field | Value | Language |
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dc.contributor.author | Lahiri, A | - |
dc.contributor.author | Hirani, P | - |
dc.contributor.author | Haghani, S | - |
dc.date.accessioned | 2024-08-21T08:28:25Z | - |
dc.date.available | 2024-08-21T08:28:25Z | - |
dc.date.issued | 2024-05-28 | - |
dc.identifier | ORCiD: Abhishek Lahirii https://orcid.org/0000-0001-8264-9169 | - |
dc.identifier | ORCiD: Sophia Haghani https://orcid.org/0000-0002-2146-0829 | - |
dc.identifier | e202400140 | - |
dc.identifier.citation | Lahiri, A., Hirani, P. and Haghani, S. (2024) 'Effect of Protic and Aprotic Formamide-Based Organic Electrolytes for Rechargeable Zinc/MnO2 Battery', Batteries and Supercaps, 0 (ahead of print), e202400140, pp. 1 - 7. doi: 10.1002/batt.202400140. | en_US |
dc.identifier.uri | https://bura.brunel.ac.uk/handle/2438/29578 | - |
dc.description | Data Availability Statement: The data that support the findings of this study are openly available in Brunel Figshare at https://doi.org/10.17633/rd.brunel.25093388.v1. | en_US |
dc.description.abstract | Zinc ion batteries (ZIBs) are emerging as a promising and cost-effective alternative energy storage system compared to other metal-ion batteries. Aqueous electrolytes have been extensively studied in Zn-ion batteries which has shown issues related to cathode dissolution. In comparison, little has been looked into the use of organic electrolytes in ZIBs. Here, we have studied both protic and aprotic forms of formamide-based organic electrolytes containing Zn trifluoromethanesulfonate and their influence on the Zn solvation chemistry, electrochemistry, and performance of Zn-MnO2 battery. It was observed that protic-based electrolytes gave a much better capacity and stability for the Zn-MnO2 battery. A capacity close to 150 mAh g−1 was obtained with formamide electrolyte at a current density of 0.25 A g−1. For all the other formamide-based electrolytes tested, the capacity was lower. After 100 cycles, an average capacity retention of 72 % was obtained for formamide-based electrolyte. This study shows that protic-based electrolytes might be a suitable option for non-aqueous-based Zn-ion batteries. | en_US |
dc.description.sponsorship | This research was funded, in whole by EPSRC. Grant Number: EP/W015129/1 | en_US |
dc.format.extent | 1 - 7 | - |
dc.format.medium | Electronic | - |
dc.language.iso | en_US | en_US |
dc.publisher | Wiley-VCH | en_US |
dc.rights | Copyright © 2024 The Authors. Batteries & Supercaps published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | - |
dc.rights.uri | https://creativecommons.org/licenses/by/4.0/ | - |
dc.subject | Zn-ion batteries | en_US |
dc.subject | manganese dioxide | en_US |
dc.subject | organic electrolytes | en_US |
dc.subject | Zn solvation | en_US |
dc.subject | formamide | en_US |
dc.title | Effect of Protic and Aprotic Formamide-Based Organic Electrolytes for Rechargeable Zinc/MnO<inf>2</inf> Battery | en_US |
dc.title.alternative | Effect of Protic and Aprotic Formamide-Based Organic Electrolytes for Rechargeable Zinc/MnO2 Battery | en_US |
dc.type | Article | en_US |
dc.date.dateAccepted | 2024-04-24 | - |
dc.identifier.doi | https://doi.org/10.1002/batt.202400140 | - |
dc.relation.isPartOf | Batteries and Supercaps | - |
pubs.issue | 00 | - |
pubs.publication-status | Published | - |
pubs.volume | 0 | - |
dc.identifier.eissn | 2566-6223 | - |
dc.rights.license | https://creativecommons.org/licenses/by/4.0/legalcode.en | - |
dc.rights.holder | The Authors | - |
Appears in Collections: | Dept of Chemical Engineering Research Papers |
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FullText.pdf | Copyright © 2024 The Authors. Batteries & Supercaps published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | 1.09 MB | Adobe PDF | View/Open |
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