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http://bura.brunel.ac.uk/handle/2438/15025
Title: | Total CCl₄ guest alignment in a quasiracemic clathrate closely related to Dianin’s compound |
Authors: | Frampton, CS MacNicol, DD Gall, JH |
Issue Date: | 2017 |
Citation: | CrystEngComm, 2017 |
Abstract: | Single crystal X-ray analysis at 100 K reveals that in the trigonal CCl4 quasiracemic clathrate, space group R3, formed from host components S-(-)-Dianin’s compound and its (+)-2R,4R 2-nor methyl analogue there is an unprecedented complete ordering of a C-Cl bond of the guest with respect to the c-axial direction. In this clathrate and that formed from the (+-)2R,4R and (+)-2R,4S epimers the participation of an unexpected host conformation is reported for the first time. |
URI: | http://bura.brunel.ac.uk/handle/2438/15025 |
DOI: | http://dx.doi.org/10.1039/c7ce01275f |
ISSN: | 1466-8033 |
Appears in Collections: | Dept of Mechanical and Aerospace Engineering Embargoed Research Papers |
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