Hydrogen sulfide removal from waste tyre pyrolysis gas by inorganics

Abstract

The article presents research on the purification process of pyrolysis gas from hydrogen sulfide. To our best knowledge, similar studies have not been performed yet on a real pyrolysis gas obtained from waste tyres, which contains huge amounts of hydrogen sulfide - average 3.6% (up to 5.1% at 420 °C). Different sorbents were tested, among them sodium hydroxide, zinc oxide, and manganese oxide. NaOH in concentration 0.05 M appeared to be the most efficient, showing ∼94% H2S removal efficiency under the conditions studied. ZnO features a better efficiency of H2S removal from hot gas (∼55%) than MnO. Furthermore, the combination of ZnO and a 0.05 M solution of NaOH was studied. The detailed composition of the pyrolysis gas was performed, too. The main components and sulfur-containing compounds, such as methyl mercaptan, carbonyl sulfide, and ethyl mercaptan, concentrations were measured. Predominantly, the gas consists of methane, hydrogen, ethane, ethene, carbon dioxide, iso-butane, and hydrogen sulfide. Aggregated concentrations of the above-mentioned exceed 80% of the gas, which makes it a very promising gaseous fuel.