Evaluating the Environmental Footprint: An LCA Study of a Pilot System Treating Potassium Mining Wastewater

Abstract

Potassium mining activities result in the discharge of highly saline wastewaters, creating severe environmental impacts in water and soil. This study evaluates the environmental performance of a novel pilot system developed in the framework of the LIFE Brine-Mining project. The system comprises membrane, precipitation and thermal technologies, recovering high-purity water and five valuable resources from it: magnesium hydroxide, calcium carbonate, calcium sulfate, sodium chloride, and potassium chloride. A cradle-to-grave Life Cycle Assessment (LCA) was performed following the standards ISO14040 and EN15804 and using 1 m3 of potassium wastewater as functional unit. The LCA results indicated that the novel system environmental impact is mainly affected by the use of chemicals (20.63 × 100 kg/FU) during its operation and energy consumption (1.39 × 101 kWh/FU). The chemical use dominates areas like the Abiotic Depletion, and the Eutrophication Potential, and the Water Depletion Potential. The novel pilot system was compared with another novel configuration that treated a brine from coal mining activities and with a conventional method of potassium brine management, which is the disposal in underground old mines. The potassium brine treatment system exhibited lower environmental impact than the coal mine brine system, and outperformed compared to the conventional disposal method.